In terms of assessing economic impact, one of the most important elements in the wood supply chain is the measurement of round wood. Besides the one-by-one measurement of logs, logs are often measured when stacked at the forest road. The gross stacked volume includes the volume of the wood, bark and airspace and is widely used for industrial wood assortments. The increasing international attention given to photo-optical measurement systems for portable devices is due to their simplicity of use and efficiency. The aim of this study was to compare the gross volumes of hardwood log stacks measured using one widespread photo-optical app with two manual section-wise volume estimations of log stacks based on the German framework agreement for timber trade (RVR). The manual volume estimations were done starting from the left (RVRleft) and right (RVRright) sides of the log stacks. The results showed an average deviation of the photo-optical gross volume estimation in comparison to the manual estimation of –2.09% (RVRleft) and –3.66% (RVRright) while the deviation between RVRleft and RVRright was +2.54%. However, the log stack gross volume had a highly significant effect on the deviation and better accuracy with smaller deviation were reached for larger log stacks. Moreover, results indicated that the gross volume estimations of higher quality log stacks were closer for the three analyzed methods compared to estimations of poor-quality log stacks.