Ashed tree samples from sound and decayed Norway spruce (Picea abies (L.) H. Karst.) were studied by means of fast neutron activation analysis, and for comparison, also by X-ray fluorescence analysis. In fast neutron activation analysis, the following elements were detected: (Na), Mg, Al, Si, K, Ca, Mn, Rb, Sr and Ba, and according to the results of the X-ray fluorescence method the elements present in the wood samples were: K, Ca, Mn, Rb, Sr and Ba. A general diminishing was revealed by both methods in most elemental concentrations studied, with exception of K and Rb, when going from a sound tree to a decayed one. The use of the ratio of the amounts of potassium to calcium as an indication of the degree of decay is therefore proposed.
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Gleysol profiles of five southern Finnish sites dominated by Norway spruce (Picea abies (L.) H. Karst.) were described according to the Canadian system of soil classification, and the total contents of five metals (Pb, Zn, Cu, Mn, Fe) were analysed in each soil profile. Lead, zinc and manganese showed highest concentrations in the organic surface horizons with a decrease towards mineral soil horizons. Vopper distribution was somewhat irregular. Iron had maximum values in the mineral soil: in A-horizon of Rego Gleysols and in B-horizon of Fera Gleysols. A preliminary comparison of metal pools in soil (root layer) with annual atmospheric input shows that the role of atmospheric deposition is relatively greater in the case of Cu, Zn and Pb than for Fe or Mn.
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