At immediate surroundings of a fiberglass plant in Central Sweden, vegetation shows toxicity symptoms. Soils and birch (Betula pendula Roth) leaves were sampled. The soil was analysed for water soluble and organic bound boron, carbon, nitrogen, and pH. Vegetation was analysed for total boron. Both fractions of boron in the soils increased towards the factory. Organic bound boron increased irregularly because of its strong correlation to carbon content which varied in the area. The C/N ratio increased nearer the industry due to the harmful effect of boron on the decomposition of organic matter. No relation between pH and the distance from the emission source was visible, but B/C ratio was found to increase with increasing pH of the soil. Boron levels in birch leaves were elevated very much close to the factory. The geographical distribution of high levels of boron in birch, corresponded well with high values in soils, and also with the main wind directions. The limit values for visible injury on birch were found to be around 5 ppm of water-soluble boron in soil and around 200 ppm in leaves.
Downy birch (Betula pubescens Ehrh.) trees growing on a drained peatland were cut during dormancy. The properties of the one-year old shoots produced by the stumps were measured in the autumn after one growing season. The one-year old willow shoots (a mixture of Salix phylicifolia L., S. pentandra L. and S. caprea L.) were collected from an abandoned field.
The basic density of unbarked shoots was 443 kg/m3 for birch and 346 kg/m3 for willow. The basic density of the bark was much higher than that of the wood. The effect of shoot length on the properties was small with the exception of cellular proportions. The fibre percentage increased and vessel percentage decreased with increasing shoot length.
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Variation of cellular proportion within the same growth rings counted from the pith of the stems and branches in four trees of Betula pendula Roth was studied. The fibre percentage decreased from breast height to the crown and then increased in the branches. The reverse trend was found in the percentage of vessels and parenchyma, although the latter varied relatively little. No statistically significant differences were found in the percentages of fibres, vessels and rays within the same growth rings counted from the pith between the stems and branches. In both the stem and the branches, the proportion of fibres increased and that of vessels and rays decreased from the pith to the surface. Even crown formed wood differed from that of stem formed.
The PDF includes a summary in Finnish.
In the first part of the study, the selected wood and fiber properties were investigated in terms of their occurrence and variation in wood, as well as their relevance for thermomechanical pulping process and related end-products. It was concluded that the most important factors were the fiber dimensions, juvenile wood content, and in some cases, the content of heartwood being associated with extremely dry wood with low permeability in spruce. The following pulpwood assortments of which pulping potential was assumed to vary were formed: wood from regeneration cuttings, first-thinnings wood, and sawmill chips.
In the experimental part of the study, the average wood and fibre characteristics and their variation were determined for the raw material groups. Subsequently, each assortment – equalling about 1,500 m3 roundwood – was pulped separately for 24 h period. The properties of obtained newsgrade thermomechanical pulps were then determined.
Thermomechanical pulping (TMP) from sawmill chips had the highest proportion of long fibres, smallest proportion of fines, and had generally the coarsest and longest fibers. TMP from first-thinned wood was the opposite, whereas that from regeneration cuttings fell in between these two. High proportion of dry heartwood in wood originating from regeneration cuttings produced a slightly elevated shives content. However, no differences were found in pulp specific energy consumption. The obtained pulp tear index was clearly the best in TMP made from sawmill chips and poorest in pulp from first-thinned wood, which had generally inferior strength properties. No big differences in any of the strength properties were found between pulp from sawmill residual wood and regeneration cuttings. Pulp optical properties were superior in TMP from first-thinnings. No noticeable differences were found in sheet density, bulk, air permeance or roughness between the three pulps.
The most important wood quality factors were the fibre length, fibre cross-sectional dimensions and percentage juvenile wood. Differences found in the quality of TMP assortments suggest that they could be segregated and pulped separately to obtain specific product characteristics and to minimize unnecessary variation in the raw material and pulp quality.
This study aimed at establishing calibrations to predict nutrient concentrations of solid moose (Alces alces L.) rumen content using near infrared spectroscopy (NIRS), as an alternative to expensive chemical analyses. NIR reflectance spectra of 148 dry pulverized samples were recorded. The scanned samples were then analyzed for crude protein, available protein, microbial nitrogen (N), ash, acid-detergent fiber (ADF), neutral detergent fiber (NDF) and lignin contents following standard chemical analysis procedures. The calibration models were derived by Orthogonal Projection to Latent Structure (OPLS) and validated using external prediction sets. The calibration models accurately predicted crude protein, available protein and ash contents (R2 = 0.99, 0.96, and 0.92, prediction error = 0.39, 0.72 and 0.53% dry matter, respectively) while NDF (R2 = 0.92; prediction error = 2.23% dry matter) and ADF (R2 = 0.89; prediction error = 1.94% dry matter) were predicted with sufficient accuracy and that of microbial-N (R2 = 0.81; prediction error = 1.25 mg yeast-RNA g–1 dry matter) and lignin (R2 = 0.84; prediction error = 1.05% dry matter) were acceptable. The ratio of performance to deviation values were > 3.0 for crude protein and available protein, between 3.0 and 2.5 for ADF, NDF and lignin, and 2.32 for microbial-N; attesting the robustness of the calibration models. It can be concluded that NIR spectroscopy offers a quick and inexpensive procedure for prediction of nutrient concentrations of solid rumen contents in wild herbivores.
At present, there are no means for reliably comparing the wood fiber contents of different material streams within the paper industry material chain with each other. The aim of this article is to introduce conversion factors that make it possible to quantify the volume of wood expressed in roundwood equivalent (RWE) values for different paper industry-related materials in the material chain. These conversion factors apply to wood pulp, paper, and recovered paper. European data are used in quantifying the paper industry material streams and calculating the RWE conversion factors. The introduced conversion factors can be used to estimate RWE volumes at a global scale. With assumption that paper recycling did not occur and that paper production volume remained unchanged, an additional volume of 666 million m3 RWEs would be required globally per annum to produce 167 million tons of virgin wood pulp to replace 222 million tons of recovered paper utilized by the paper industry in 2010. This volume is approximately the same as 1.6 times the total removal of wood in Europe (EU27), or the total annual removal of wood in the USA, Canada, and Brazil combined.